Week 6 brought six upsets among the Top 25 and vote-getters. The remainder of the Top 25 and vote getters held rank in 47 matches during Week 6.
No. 10 Nebraska continued its climb back up the rankings, delivering upset wins over No. 4 Minnesota and No. 7 Wisconsin.
No. 6 Washington was upset by No. 16 USC and No. 22 Colorado bested No. 12 Oregon. No. 24 Florida State dropped road matches at Louisville and Notre Dame (RV).
| Date | Winner | Loser | Results |
| Sept. 26 | #8 BYU | Pepperdine | 3-1 (25-17, 18-25, 25-21, 25-21) |
| #23 Colorado State | Wyoming | 3-0 (25-17, 25-21, 25-13) | |
| #25 San Diego | Loyola Marymount | 3-0 (25-22, 25-22, 25-20) | |
| Sept. 27 | #3 Stanford | Arizona State | 3-0 (25-12, 25-18, 26-24) |
| #5 Texas | #21 Baylor | 3-0 (25-19, 28-26, 25-17) | |
| #9 Kansas | #20 Iowa State | 3-2 (25-27, 20-25, 25-20, 25-16, 15-11) | |
| #19 Purdue | Indiana | 3-0 (25-23, 25-13, 25-19) | |
| Marquette (RV) | Xavier | 3-1 (20-25, 25-22, 25-19, 25-13) | |
| Sept .29 | #1 Florida | Tennessee | 3-0 (25-17, 25-18, 25-19) |
| #3 Stanford | Arizona | 3-0 (25-21, 25-21, 25-7) | |
| #10 Nebraska | #4 Minnesota | 3-0 (25-21, 25-18, 25-13) | |
| #2 Penn State | Illinois (RV) | 3-0 (25-19, 25-17, 26-24) | |
| #6 Washington | #17 UCLA | 3-1 (18-25, 25-20, 25-22, 25-15) | |
| #7 Wisconsin | Iowa | 3-0 (25-17, 25-22, 25-17) | |
| #12 Oregon | #14 Utah | 3-2 (25-16, 25-13, 16-25, 17-25, 21-19) | |
| #13 Creighton | Seton Hall | 3-0 (26-24, 25-12, 25-21) | |
| #15 Northern Iowa | Bradley | 3-0 (25-14, 25-11, 25-12) | |
| #18 Michigan State | Maryland | 3-0 (25-14, 25-14, 25-21) | |
| #20 Iowa State | Texas Tech | 3-2 (25-27, 23-25, 25-19, 25-21, 15-12) | |
| #22 Colorado | Oregon State | 3-2 (25-21, 25-27, 25-23, 7-25, 15-12) | |
| Louisville | #24 Florida State | 3-0 (25-20, 25-20, 31-29) | |
| Michigan (RV) | Ohio State (RV) | 25-15, 25-20, 22-25, 25-22) | |
| Wichita State (RV) | USF | 3-0 (25-15, 25-17, 25-10) | |
| Western Kentucky (RV) | Louisiana Tech | 3-0 (25-21, 25-15, 25-16) | |
| Cal Poly (RV) | Long Beach State | 3-1 (26-24, 25-10, 16-25, 25-18) | |
| Miami (Fla.) | Notre Dame | 3-1 (25-22, 25-23, 11-25, 32-30) | |
| Hawaii (RV) | Cal State Fullerton | 3-0 (25-8, 25-9, 25-16) | |
| Sept. 30 | #4 Minnesota | Iowa | 3-0 (25-23, 25-22, 25-19) |
| #2 Penn State | Northwestern | 3-0 (26-24, 25-14, 25-14) | |
| #5 Texas | Kansas State | 3-0 (25-17, 25-12, 25-16) | |
| #10 Nebraska | #7 Wisconsin | 3-2 (22-25, 17-25, 25-20, 25-23, 15-8) | |
| #8 BYU | #25 San Diego | 3-1 (25-23, 23-25, 25-20, 25-18) | |
| #9 Kansas | TCU | 3-0 (25-22, 25-17, 25-21) | |
| #22 Colorado | #12 Oregon | 3-1 (25-18, 24-26, 25-19, 25-18) | |
| #13 Creighton | St. John’s | 3-0 (25-15, 25-20, 25-19) | |
| #14 Utah | Oregon State | 3-0 (27-25, 25-16, 25-17) | |
| #15 Northern Iowa | Illinois State | 3-1 (25-20, 24-26, 25-13, 25-21) | |
| #16 USC | Washington State (RV) | 3-1 (25-15, 25-27, 25-12, 25-19) | |
| #18 Michigan State | Ohio State (RV) | 3-0 (25-13, 25-18, 25-17) | |
| #19 Purdue | Indiana | 3-0 (25-16, 25-14, 25-15) | |
| #21 Baylor | Oklahoma | 3-1 (25-10, 19-25, 25-14, 25-23) | |
| #23 Colorado State | Air Force | 3-0 (25-21, 25-19, 25-19) | |
| Michigan (RV) | Maryland | 3-1 (25-19, 19-25, 25-15, 25-21) | |
| Cal Poly (RV) | Cal State Northridge | 3-0 (25-19, 25-20, 25-20) | |
| Marquette (RV) | DePaul | 3-0 (25-19, 25-9, 30-28) | |
| Hawaii (RV) | UC Riverside | 3-2 (20-25, 19-25, 25-20, 25-19, 15-7) | |
| Oct. 1 | #1 Florida | LSU | 3-0 (25-17, 26-24, 25-23) |
| #16 USC | #6 Washington | 3-0 (25-20, 25-21, 28-26) | |
| #11 Kentucky | Mississippi State | 3-0 (25-21, 25-20, 25-16) | |
| #17 UCLA | Washington State (RV) | 3-1 (25-12, 25-12, 22-25, 25-13) | |
| Notre Dame (RV) | #24 Florida State | 3-2 (25-21, 23-25, 19-25, 25-12, 15-12) | |
| Wichita State (RV) | UCF | 3-1 (21-25, 25-20, 25-12, 25-15) | |
| Western Kentucky (RV) | Middle Tennessee | 3-0 (25-15, 25-17, 25-20) | |
| Illinois (RV) | Rutgers | 3-0 (25-11, 25-16, 25-18) |
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